You are a clueless f****it. PVC burns with a lot less energy released per unit mass than polyethylene but it still burns exothermically if there is sufficient oxygen available or at elevated temperatures.
PVC self ignition in air is at about 450C according to:
and
HCl emission, free radical quenching and charring helps slow the burn rate although the resulting fumes are not good to breathe.
Even carbon tetrachloride will burn exothermically if you provide it with enough oxygen but in air at STP it works very well as a far to toxic to use these days fire extinguisher.
I recall just how impressive a tiny hand held car BCF extinguisher was from fire training. I think halon is only allowed in aerospace now.