A little bit loosely DIY, I guess, so apologies to any purists:
>
> Last week I fitted some new brake blocks to my bicycle, a 15-year-old
> Peugeot model with steel/chrome rims. The blocks are definitely for steel
> rims. They work fine but the front brake squeals so loudly it's
> embarrassing (it certainly makes a horn or bell redundant). The rear
> brake is silent, and yet the blocks and rims are identical to those on the > front. >
> Anyone have any advice on what I can do to the brake to stop the squealing?
A perennial problem. Two possibilities: try sand papering the faces of the new blocks.
Clean the rim with white spirit and vigorous rubbing, rubber from the old blocks adhering to the rim can cause the problem too.
Peter