Best way to clean brown stains from toilet bowl ?

Oct 24, 2025 Last reply: 8 months ago 33 Replies

For reasons unknown, one of our toilets has developed a rather unsettling brown stain around the bottom.



We live in the softest water area in the universe (it would seem) as our kettle still looks new 15 years on. (SW Brum, in case you ask. Thank god for Welsh water :) ). S



o it's not limescale.



Anyhow some basic research suggested peroxide, so I dult emptied the bowl, sprayed and scoured after 30 mins. And 80% lifted with a touch of elbow grease. However the remainder seems a little bit more stubborn.



I see suggestions around citric acid and white vinegar - neither of which we have lying around. I'm willing to fork out if I have a degree of certainty (because I am getting as housebound as SWMBO, so everything is a delivery).



What would the group use ?


I use thick bleach. Works for me. We're in a hard water area if it makes any difference.

If peroxide worked, after a fashion, try a stronger oxidising agent…bleach…

People often suggest bleach, but ISTM that all that does is whiten whatever is the problem. Does it feel rough? If so, it might be scaling of some form so an acid will be the answer. Interested to hear back what you find solves it.

Exactly! I remember cleaning some dishes with bleach many years ago and they looked beautifully white until they were used again when all the old stains sort of redeveloped immediately.

First try hydrochloric acid (spirits of salts) in case it's alkali-based or iron-based. Leave overnight if possible. Flush well.

If you want to try a peroxide-based treatment, get one of those 500g tubs of oxidising bleaching powder based on sodium percarbonate (sodium carbonate perhydrate). Lidl do one (Almat Oxi-Fix). Put a heaped tablespoon of it in the bowl, and leave overnight again if possible.

Strong household bleach, neat. Just fill the bowl up with about half a litre and leave it overnight

>

Yup. Citric acid for scale and bleach for stains

Id does break down organic stains though.

That rather unlikely with peaty water. Sadly porcelain glaze does develop surface crazing over time.

can use usual abrasives to polish it out

One thing I wouldn't use is anything which might damage the porcelain's surface. That would make it much harder to keep clean in future. I winced at your mention of "scoured", but I imagine you used a plastic scourer, not wire wool or its ilk.

Glass is surprisingly resistant to scratching. Especially if yoiu use somnething like 'vim' etc

For those in hard water areas suffering from limescale, brick acid is probably the easiest & cheapest method.

Beware. It turns chrome black. It isnt great for iron or copper either.

It is simply too strong.

You can get e.g. Citric acid in 'appliance descalers' that is kinder to the metals. It's about £2-£5/kg depending on purchase quantity

You just have to be patient...

Tried and tested recipe:

Make a big batch of Elderflower Wine. Discover that it tastes absolutely awful so decide to distil it into schnapps.

Pour the schnapps into a bottle and the residue down the toilet.

All stains completely gone.

Nick

Yes, I should have made clear that the use of brick acid was for toilet bowls & ceramics.

The problem is you do not know what is downstream of a toilet, Iron pipe perhaps?

<xxxx>>

Also eBay, similar price, usually free delivery.>

-- SS

Alternatively...

Decide that now is the time to completely revamp your bathroom. I hear that brown is very much this year's colour! [1]

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Nick [1]When my grandmother was a dental nurse at Ashford Dental Hospital[2] in Middlesex during the 1950s I often puzzled about why the "Recovery Room" was painted floor to ceiling in bright red. Dentistry was different in those days... [2]Attached to the main hospital building, in case you wanted to know.

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"Studies have shown that elderberry and elderflower extracts possess diverse biological activities such as anti-inflammatory, antioxidant, and antidiabetes effects [12,13]. S. nigra has components with high biological activity, primarily flavonoids, such as flavonols, proanthocyanidins and anthocyanins, and simpler phenolic acids [12].

However, due to the complex bioavailability of polyphenols, it is difficult to know what the most relevant substance is after intake of elderberries and elderflowers in humans. Due to the fact that polyphenols are metabolized to simpler phenolic substances [14], it was also of interest to investigate whether these metabolites could contribute to an effect. "

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"Updated October 14, 2022 Phenol

Phenolics, including carbolic acid, are a family of compounds commonly referred to as simply "phenol". This chemical was one of the first antiseptics used to sterilize medical equipment, but can also be mixed with other ingredients to

clean toilets,

floors, drains, and other items. "

You might be onto something, professor :-) Nature finds a way.

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It might even be working on the limescale and the brown organic at the very same time. Saves on having to switch cleaning strategies over and over again. Read MSDS first before using.

For my first ghetto chemistry, I would try preparing the material out of doors, rather than doing that indoors. If nothing tips over or catches fire... maybe it is safe.

Paul

AIUI, brown stains in the loo can be of two sorts; thin poo smears that never properly flush off and just discolour the porcelain, and iron staining from the water.

If the former, a good scrub with a loo brush will normally get rid of them. Better, pour a little neat bleach all around the inside of the rim, let it dribble down into the bowl. let it soak there for a few hours, like overnight, then flush the loo and follow with a good scrub with said loo brush.

If the latter, oxidative bleaches such as 'bleach' or hydrogen peroxide won't be very effective. You need a reductive bleach such as Dr. Beckmann's colour run remover. E.G.

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sold as being for restoring fabrics who's colour has run, it contains sodium dithionite (AKA sodium hydrosulphite or Hydros), a strong reducing bleach widely used in industry. Dissolve a small amount in some water, pour into the loo, give it a stir and leave overnight.

Caveat: I've never used it for cleaning loos, as I don't get iron staining, so you use it at your own risk!

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