Well, aren't there a lot all of a sudden.
A thread that wnet tangential on uk.l.m caused me to do some reading:
Honeywell Evohome - the new CM-Zone - RF rad valves, central multizone capable, boiler relay, internet control (but not web it seems, just apps)
HeatGenius - Uses a number of other people's ZWave devices like the Danfoss ZWave TRV head, Horstman boiler relay (IIRC) and other bits like PIR sensors for occupancy combined with what I assume is HeatGenous's own special controller to create an internet enabled smart CH control with multiple zones (like NEST, self programming schedules)
Both systems v.expensive but you could buy the TRVs incrementally I guess.
Tado - single zone, cheaper, uses phone app to form a GeoFence and automatically heat your house when you are coming home. This one is unique in that it can (optionally) sit on your boiler's eBus and even feed you error reports as well as commanding the boiler.
NEST - single zone, but looks like it was invented by Apple (because it more or less was - well ex Apple folks).
Anyone seem any of these in action?