That depends on your halon, and whether you've done something as radical as spraying it onto a fire. The aircraft and confined-space halons (halon 1340 ?) are deliberately chosen to have less-toxic combustion by-products than the commonplace halon 1211.
I keep about 15kg of halon in the workshop, but as it's hard to replace I don't use it. I'd have to have a serious hydrocarbon fire before I went for those - little stuff or electrics would get hit with dry powder, or water for timber.
So far my only workshop fires here have been sawdust in the extractor (bucket of water) and a very small titanium fire (stand back and watch the pretty fireworks).