Glad the D.000 change helped I have the Pump set to Comfort mode (1) Also D.002 Anti cycling time reduced from 20 mins to 6 mins. This better reflects the way my EVOHome thermostat controller works and the needs of my large Victorian house spread over 4 floors and its room occupancy.
In hindsight I should have gone with the less Green Valiant ecotech plus boiler. I do think these super green boilers are trying too hard to minimise CO2 emissions with programming algorithms which no-one understands. While probably suitable for a well insulated house with most rooms in use all the time they seem ill suited to older larger properties.