There is H&S document on this.
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backboiler behind a real fire (or box-tank behind a gas fire) works by recovering heat from flue gases, said heat then being used to pre- heat a HW tank or radiator. Decommissioning such back boilers (or either type) must be done correctly.
Immediate risk - explosion Water left in the tank which can not circulate or vent will superheat
- eventually rupturing or even exploding.
Secondary risk - flue gases If pipes are left vented the tank will eventually corrode permitting flue gases to be transferred elsewhere, posing a serious CO risk.
The proper solution is...
- Remove the pipes
- Fill holes occupied by pipes with fire cement
- a) Fill the tank with sand & leave ventilated to the flue only
- b) Remove the tank from the fireplace and refill with suitable bricks, refractory lining as necessary
They are actually quite good at heating water with a gas fire. However I suspect the decommission cost is rather high even if a simple "box tank". More substantial dismantling is properly rather expensive - anyone know?
Beware such backboilers exhibit a winter flood risk when the house is unoccupied. Cold air plunges down the chimney and over days can cause the tank &/or pipes to split - the resulting flood from the CW-HW tanks is either unlimited or still 800L if you have the CW isolated. I've known 3 fail in this manner, wrecking expensive wooden flooring and downstairs contents throughout (DG doors meant the water literally had nowhere to go with solid floors throughout).