You could with a Pressure reducing valve and Safety valve(s). It's living dangerously, though. Domestic hot water tanks are paper thin and neither valve is particularly reliable or precise. It's an unvented cylinder and you should have the G3 ticket to install them. It should also be a factory assembled kit.
An immersion heater would introduce a whole new range of potential excitement. Some unvented cylinders work like this (Tribune ISTR???) but the copper cylinders are/were more robust.
Stainless steel cylinders are now more common, given the price of copper.