When we first replaced our tungsten bulbs with daylight CFLs, they seemed very blue. The difference between the bedrooms with daylight and the bathroom with tungsten GU10s was very noticeable - tungsten looked horribly yellow.
I don't notice the difference between the two as much now. What I do like about daylight bulbs is that the inside of my study is now the same colour as the daylight coming through the window, whereas before the difference was very noticeable. The only problem with that is that occasionally I forget that I've left the light on during the day and go out with it still on!
It's quite an eye-opener to see the spectrum of a typical CFL and how many peaks it has - not exactly black-body radiation :-) It's amazing that the colour rendition is as good as it is with peaks and gaps like that.
I've always wondered why daylight slide film made fluorescent lights look a horrible green colour (even when they were probably warm-white around
3500-4000K) whereas you don't get that with a digital camera. The green emulsion of the film must have been unusually sensitive to one of the lines in a fluorescent tube, in a way that the green pixels of a digital camera aren't to the same extent.