I have 3 pressure vessels on my heating system. You can't check pressure charge on air side when water in system, so had good advise to fit FLAMCO 3 way valves You have it set to system (normal) or set to drain where you can depressurise the vessel without draining system.
Q ... Existing set up is as per this pic-
I would fix Flexcontrol valve to top top of pressure vessel and then fix pressure valve & filling loop set to this.
On this pic you can see there are 2 types of 3/4 BSP valves.