My neighbor likes me to spray Lowes glyphosate with surfacant along buildings and fences. I want it to work fast because she'll get antsy and want me to use a string trimmer. You can't argue with a woman.
Typically, the effect isn't visible on most plants in 3 days. It's quite visible in a week. The other day I noticed the brown leaves of poison ivy I'd sprayed at her place.
At my place, I don't bother to spray poison ivy. It's easier to snip with hedge shears. If it comes back, I snip again. Glyphosate is good for the kind of plants that would come back quickly and persistently.
I first used glyphosate on poison ivy about 1983, at the farm. It was a patch covering hundreds of square feet. Spraying worked fine. When I sprayed a patch a few years later, I saw no effect after a week. Maybe it wasn't growing when I sprayed.
I've never had trouble attacking poison ivy with a string trimmer. Maybe it happens too fast for the plant to bleed.