| Unlike some here, I love WD-40, but I think something like Liquid | Wrench would work better to unstick stuck screws. Maybe it's thinner?
In this case it's also hard to get it in there. The screw head points down when the water is off. I'd have to turn off the water just to leave the screw in a horizontal position. There's no way to leave it so that the liquid can soak in.