Between 35 and 50 psi are the figures I've seen quoted. These were very high pressures for the day (and would remain respectable for another 35-odd years in railway applications).
It was geared down for low speed. Hauling unsprung waggons on plate rail, you'd not want to go faster. Speeds of 3-5mph or so were typical for plateway locomotives, certainly as long as cast-iron plates stayed in use (say
1850s at Dowlais). You'd not want to go faster, given that you needed to carry platelayers on the train to replace the rails that had broken under you..It's often forgotten that the Pen-y-Darren machine was not designed as a locomotive, but was an adaptation of a multi-purpose stationary engine. Nonetheless, it managed the longest continuous run undertaken by any locomotive until 1825..