You have to open the windows at night to gain some headroom as well.
It will eventually reach the same temperature of the air outside if there is any exchange of air going on. The point is that it doesn't get significantly hotter than the air outside like it would in a greenhouse!
Your only other option then is a fan to move what air there is around a bit and aid evaporation from your skin. That will feel cooler. My office fan has three settings low, medium and high. They should more properly be called gale, storm force and hurricane. None of them are compatible with having any loose paperwork on my desk.
So far it hasn't been hot enough to merit using it provided I do most of my office work provided I give up mid afternoon.
You are not doing it right then or your expectations are completely unreasonable (probably both). You cannot expect to cool something in direct sunlight using any sort of conventional material all you can do is slow its rise in temperature.
If you really want to cool something in direct sunlight then you need expensive metamaterials which are mirror finish or white for visible and near IR radiation and black in the 10um thermal band.
Some progress has been made with mass producing metamaterials. I am a bit sceptical how well they work with grime and bird lime on them.