I've bought some nubuck cleaner that I haven't used before, it has that typical nail polish pear-drops smell, so I checked the MSDS and the only "active" ingredient it listed was 1-5% isopropyl alcohol, which I know doesn't have that acetate type of smell.
Actually when I checked the manufacturer's website they do have an ingredients list separate from the MSDS, which lists butyl acetate as well as the IPA.
Could the acetate be such a small component, yet so pungent that it doesn't require listing?
It seems to work very well, lifts out dirt/stains well, hasn't fully dried off yet, but no darkening.