I've had a survey for cavity wall insulation, but it's going to be nearly £400, for a bungalow with large windows (because of a car port in the way, even though the wall above it only has an upstairs bathroom the other side). So not sure if it's worth the trouble.
But just did an experiment with a piece of sleeping mat held against an outside wall (8-10mm foam). After about an hour, the surface of the mat was at 16.4C, the bare wall next to it was at 15.1C, and the wall under the mat was 13.8C (the opposite interior wall as at 17.7C). (All measured with a cheap infra-red thermometer.)
Is there any thin insulation like this, specially designed for putting on walls? I've only seen 2" thick stuff designed to be inside some sort of extra wall. (I'd be happy with pieces of sleeping mat, except they're not cheap, and I'm not sure how fire-retardant they are, among several problems...)