Not worth defragmenting the original disk at this stage. The files will be turned into contiguous ones on the new driver during the copy phase.
Incidentally defragmentation of an SSD does nothing useful at all and shortens its working life. Certain OS settings should be reconfigured when an SSD is fitted. I think the utilities that come with them these days will do it for you. Things that make sense on spinning rust make no sense at all on solid state drives where seek time is near zero.
+1Running windows to try and rescue a bad disk will almost invariably make things worse. Especially if the damage is on the same drive as the system swap file. It can do additional damage due to making simple minded "repairs" that will turn the problem from mostly repairable with a few minor losses using the right disk recovery tools to mostly wrecked with a few lucky files that can still be recovered.