Shouldn't be a problem, if you can find all the suitable adaptors.
But the expansion vessel can go anywhere on the supply or return pipework to the radiators. There's a lot to be said for fitting them on a flexible connection (like the filling loop). One thing I would recommend is fitting a ball valve for isolation, so that you can test and when necessary recharge the vessel easily without depressurising the main system. (You should fit a drain point downstream too, otherwise you will have to release pressure by cracking a compression fitting). And obviously, remember to de-isolate afterwards.