Hello Tor;
A multiple group mold isn't really necessary, and it's a lot more work to make multiple identical masters. It's better for consistency to make up one master, and make a bunch of individual silicone molds from it.
For example, with the pickup bobbins that I use in my basses, I need 8 bobbin halves per instrument. I machined up an aluminum master, then made up 8 silicone molds from it. Now I can mix up one little cup of urethane and pour a full instrument set of bobbins in one shot. If and when any of the molds get damaged, I'll make up new ones as I need them. The important thing is that all of the molds came from the same master, so that the parts will always be identical.
The hard urethane that I use is very easy on the silicone molds. I generally use mold release spray for good practice, but it isn't absolutely necessary with the urethane. Casting epoxy is another story. Without a good coating of mold release, epoxy will pull chunks out of a silicone mold.
I don't remember having any urethane "go bad". It's a 50/50 mix and it isn't that fussy. If you really screwed up the mix, it probably just wouldn't harden. I use a pair of little stainless steel kitchen mixing spoons, and count out so many spoonfuls of each part into two paper cups. I visually check the levels of the two cups, side by side, pour one into the other, stir for 15 seconds, and pour into the mold.
Urethane is great for all kinds of small parts. It sets up very quickly, typically less than 10 minutes, but it takes about 30 minutes before it fully hardens. After casting, it machines easily. One drawback to hard urethane: it's naturally white, and you can use pigments to make it any color, except black. Adding black pigment will make it smoke grey, but it won't go black. I'm not sure about the softer urethanes. I make my pickup bobbins smoke grey, and then finished pickup coil goes into another mold and gets overcast with black epoxy.
Bruce Johnson Johnson's Extremely Strange Musical Instrument Co. Burbank, CA