g'day joggerman,
seems to be a bit of hype around about roof water usage, the major contributor will be the sort of cladding you have on your roof, most have clay tiles or metal so be no problems with that water even for drinking.
as for what is in the rain well that can be another story, might be some factors in nearness to industry belching out pollution or major thoroughfares with their pollution.
i cannot see any problem using rain water collected for vegetables for one whatever is in rain water for the main settles to the bottom of teh tank out of harms way, and is any of it realy in a solluable for to be taken up by plants through the mycorzoria or worms actions?
anoteh with the watering process with vegetables we only ever water the root zones of plants not over the foliage as wetting the foliage can cause other issues like encuraging mildews etc.,. also root zone watering is the most efficient use of water along with mulch to keep that water from evaporating.
we use rain water some for drinking our tank 22.5k/litre size as sedimanet in the bottom as did our tanks on our our previous property we don't routinely get sick.
i would suggest as their may be pollutant matter falling onto you garden anyway again depending on your proximity to a polluting factor, that for above ground leaf and fruit crops you simply wash them before eating them raw. my sugestion also would be anything that may be left on those above ground crops from your watering would be washed away with the next shower of rain.
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