That's an interesting possibility but I'm not sure if it would be possible with our boiler. After living in a house with ducted warm air heating for the last 35 years I'm seriously lacking in experience with radiator systems so any comments and advice will be welcome.
To summarize my original post, we've just bought a house where there is no room stat and only the bedrooms have TRVs. The "standard" approach of a room stat in the living room and TRVs everywhere else doesn't appeal since there will be times when we'll want to heat parts of the house without heating the living room. Separate zones would obviously be the best solution but I don't fancy the task of ripping up floors and modifying the pipework layout to achieve this so I was considering fitting TRVs to all the radiators and relying on the boiler's internal bypass.
I was back at the "new" house last week and picked up the manual for the boiler. It's a Worcester Bosch "350 Combi" (HC350.FSN), probably about 4 years old. The boiler has a single heat exchanger in the combustion chamber, this normally feeds the CH circuit unless there's demand for DHW when the CH pump stops and a separate pump starts up to divert the flow to a water to water heat exchanger to provide DHW. In case my description isn't clear I've put a copy of the boiler water flow diagram on . As I said I'm a newbie to radiator systems so I don't know if this is an unusual design or not.
It looks to me that an extra CH pump would have a detrimental impact on the DHW mode by stealing some of the flow intended for the heat exchanger unless it was connected across the flow and return lines with a motorized valve (or a couple of non return valves) and configured to cut in only when the flow valve sensed that all the TRVs had closed. Since the extra pump would always be pumping into a "blocked" line I suppose it would also need it's own bypass valve. I suspect I'd end up with an overly complex setup just to avoid a bit of boiler cycling.
The boiler manual claims that "the electronic controls prevent rapid cycling of the appliance in the central heating mode" but fails to go into any detail. I suspect this is achieved by an imposed minimum "off" cycle of 3 minutes which is mentioned elsewhere in the manual.
I suppose it all boils down to whether the cost of the fuel wasted in cycling the boiler is sufficient to justify the cost of installing a more complex control system.