No? This is unusual logic. It both emits and absorbs radiation, but it doesn't absorb IR? :-)
I don't think so. Try it. I've pointed my Raytek at night skies and daytime skies, with clouds, and read similar very cold temperatures. When I point a $1K Exeltech at the same cloudy sky, I read a much higher temp. I think the Raytek measures emissive power in a narrow wavelength band that excludes the strong water vapor absorption bands around 1, 1.4, and 1.8 microns, but the Exeltech looks at more of the spectrum.
Nick