The message from Si contains these words:
Not in normal situations. If you subtract the outlet temperature from the inlet you get the average temperature of the radiator. Taking the temperature in the centre merely short circuits that calculation. Temperature decay is dependent on temperature difference so the centre is not quite average but within the limits of the exercise you are carrying out it and the thermometer you are using it matters not a jot. And you get the added bonus that your results are less likely to ruined by measuring the temperature of the wall rather than that of the pipe.
If you have clip-on thermometers you are stuck with measuring the pipe temperatures but have a bit less need to get simultaneous results which is a good thing as using clip-ons may take you 10 times as long.
No. Just fully open the TRVs. Opening the windows will introduce an unwelcome variable into the equation. As I said above speed is of the essence but it takes very little time to go round the house pointing an infra red thermometer at each radiator and recording the result, and as a precaution you can measure the first one again at the end of each circuit.
When all is said and done all you are trying to do is to get approximately the same flow rate through each radiator. The TRV will control the actual room temperature which is why cowboy installers don't waste their time balancing radiators.
You do need to make sure that the radiator without a TRV which you should have in the same room as the room thermostat is not favoured over the other radiators otherwise the remainder of your house might take too long to get up to temperature.