You need to build a 'heat dump' into the system to allow for this.
I have a system with 30 Navitron tubes, but a reasonably small cylinder (due to space issues) so have built in a heat dump mechanism to deal with this. The cylinder coil used for the HW primary circuit goes via a towel radiator in the bathroom before returning to the boiler (so in 'nornal' boiler heating mode the water goes boiler, pump, zone valve, cylinder, towel rad, boiler), so when heating water the bathroom rad gets hot too.
I use an 'excess cylinder heat' output from the solar controller to enegize a relay, which:
Disables the bolier 'call for heat' input, so the boiler *cannot* fire, in-case a stat is at a stupidly high setting,
Energizes the HW zone valve, which in turn energizes the CH pump.
This causes water to flow from the cylinder coil to the towel rad, then onto the boiler (which is off) before returning to the cylinder. This has proved to be very effective at preventing the system going beyond a sensible limit - heat dump triggers at 80 degrees and system has never reached 85 degrees.
There is a data logger on my solar contoller, and when I have plotted the data to a graph the effect can be seen clearly.
HomeOwnersHub website is not affiliated with any of the manufacturers or service providers discussed here.
All logos and trade names are the property of their respective owners.