I've now located the leak. It's on one of a pair of automatic air-vents. Easily fixed by replacement, if a bit of a fiddle, requiring partial drainage of the system etc.
But I'm wondering if they're really necessary in my situation. When the c/h system was installed in the bungalow, some twenty + years ago, the air-vents were at the highest point in the system, where they should be. But we've since had a dormer room put in, with a radiator, which means the top of the radiator is now the highest point, and I bleed that radiator once or twice over the winter months to vent trapper air.
So is there still a need for automatic air-vents that are no longer at the highest point in the system? I've a mind just to cap off the stub pipes with stop-ends and be done with it. Would that cause problems? The boiler is a Vaillant ECOmax VU226E, which AIUI has its own internal automatic air-vent anyway.