Go for it. It isn't brain surgery. Just buy a few extra fittings, and a couple extra feet of pipe, so you have something to practice on before you tackle the real thing.
One thing I'm not sure I've seen anyone mention yet in this thread: apply heat to the _fitting_only_, not to the pipe. The idea is to expand the fitting slightly, to make a larger gap for solder to flow into -- so that when it cools and shrinks, you have a tight and leakproof joint. There's enough contact between the fitting and the pipe that the pipe will get hot enough to melt the solder even without being heated directly by the torch.
Then apply solder to the _pipe_ just outside the joint, but not to the fitting. If you have everything cleaned, fluxed, and heated right, the solder will melt and flow into the joint.
-- Regards, Doug Miller (alphageek at milmac dot com)
Nobody ever left footprints in the sands of time by sitting on his butt. And who wants to leave buttprints in the sands of time?