Your premise is quite correct, but I'm not so sure about your conclusion.
Yes, a gallon of fuel contains a fixed amount of energy, but an internal combustion engine can't get 100% of that energy to the wheels. So what all the pipe dreams are about is trying to squeeze as much of that available energy from that gallon of gas as possible.
While preposterous ideas and claims abound, it would be wrong to imply that there is no possibility of mechanical improvements that would increase efficiency.