Loads of trains of thought to follow. House is heated by conventional radiators but of course this time of the year are not needed. The front of the house with three of the bedrooms faces SE and the rear with one bedroom, ensuite and bathroom faces NW with a nice big red brick wall facing SW. So do I assume that it is this wall that is collecting all the heat? If this is the case I also guess there is very little I can do about it as I do not want to paint it White.
Another train of thought was heat travel via the loftspace. It is of conventional construction with the cavities open at the top where the roof is resting. Could the heat be rising out of the cavity at night in to the loft space and then building up?