Any line with ADSL through BT wholesale will connect to any ISP which hooks up to BT wholesale, IME. BT use the username to work out which ISP to route the session to - there's no hardwired connection to your ISP. The ISP might choose to reject it if it's not coming from the expected phone line, but I don't know of any which do this. I used to have AAISP on one line and BT business ADSL on another, and it didn't matter which line each modem was connected to - it was the login which decided which ISP you got, not which line you used.