If it's an older car, could have a quite marginal alternator. I changed the original 65 amp one on my SD1 for a current design 100 amp unit. Needed a bit of fiddling to fit it, but nothing I couldn't manage. Got it off Ebay new for about 1/4 the cost of a new battery. ;-)
You need to set it to current (amps) remove one battery terminal and insert the meter in series, with everything on the car that can be switched off. Best to short across the *meter* in some way when re-connecting the battery as the switch on surge could be quite high and damage the DVM, or blow its fuse. Once the battery has been re-connected for a few seconds, remove the short.
You should see a reading of no more than 20-40 mA. (0.02-0.04 amps)