Can not quite see what I am looking at, but...
Is it still plumbed in to an immersion tank, with water in it?
- If there is water in it and the whole lot freezes (cold air descends) you can actually defrost the front half with a fire, but not the rest and the boiling water can result in an explosion. It is rare, but has happened - bungalows seem to be more vulnerable perhaps re smaller chimney run when left empty.
- If there is no water in it, the fumes from the fire can be drawn somewhere else - creating secondary fire or carbon monoxide poisoning. This is particularly dangerous with open flue gas fires which can create quite a bit of CO which can wander elsewhere, but other materials burnt in a fireplace are not exempt from this fatal scenario.
Check the chimney itself is intact and fit for usage.
- If there is a second upstairs chimney are the feathers ok (bricks separating them), otherwise you can get gases & heat migrating.
- Likewise is the chimney fit for high temperatures created by burning coal and that ubiquitous bit of wood that gets thrown on there, because just about all the coal burners used to get wood in them if coal had not been delivered. Failures in internal structure can result in joists being set on fire.
An empty back boiler should be filled with sand completely, ideally removed. Do not leave open pipework because products of combustion can go somewhere else. Think the HSE has something to say on this.