I know that generally people seem to think that blue MDPE pipe is for burying and that black is for above ground use but I can't seem to find that actually stated explicitly anywhere.
The BES web site
Another site I have found says "Available in Blue for Drinking Water Supply" and "Available in Black for Irrigation Supply".
Aha, I think I've answered my own question, I looked for the relevant British Standards (that I got from the BES site), and they are:-
BS 6572 : 1985 Blue polyethylene pipes up to nominal size 63mm for below ground use for potable water
BS 6730 : 1986 Black polyethylene pipes up to nominal size 63mm for above ground use for cold potable water.
That's pretty definite! :-)
So you can have hot water underground in MDPE but not above ground!
What happens if you use black underground or blue above ground?