I have and I've filled hundreds of tanks. The oxygen is the same from the main tank. The difference is the tanks themselves. Medical tanks are also tagged with lot numbers for traceability. Must also meet USP specs for purity.
It makes sense for the oxygen company to go with the highest level of purity in all cases.
Don't forget about aviation grade too.
I do not know what co. you work for but it seems that gas you have seen it has being purified and filtered before it got there, Organization I witnessed are in recovery business of few different gases.